least polluting rocket fuel
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psturroc@gmail.com - 25 Jan 2006 15:17 GMT Are there any rocket fuels -- existing or potential -- that are less polluting than kerosene or hydrogen? If so, are any of them economically feasible?
Roy Smith - 27 Jan 2006 04:10 GMT > Are there any rocket fuels -- existing or potential -- that are less > polluting than kerosene or hydrogen? If so, are any of them > economically feasible? I can't imagine anything less polluting than hydrogen. The only possible combustion product of hydrogen is water, regardless of temperature or mix ratio.
Ian Stirling - 28 Jan 2006 21:52 GMT >> Are there any rocket fuels -- existing or potential -- that are less >> polluting than kerosene or hydrogen? If so, are any of them [quoted text clipped - 3 lines] > combustion product of hydrogen is water, regardless of temperature or mix > ratio. Several people have mentioned this, but it's not quite true. Of course, only water comes from the reaction of oxygen and hydrogen.
But, when a several km/s jet of any form hits air, it's quite hot and energetic enough to cause nitrogen oxides to form.
no_one - 27 Jan 2006 13:05 GMT cold gas (nitrogen) is a non polluting but its Isp is probably not what you are looking for. Why do you think that hydorgen is polluting? I would think that the post combustion product was H2O.
> Are there any rocket fuels -- existing or potential -- that are less > polluting than kerosene or hydrogen? If so, are any of them > economically feasible? Ten Quidado - 27 Jan 2006 17:41 GMT > Are there any rocket fuels -- existing or potential -- that are less > polluting than kerosene or hydrogen? If so, are any of them > economically feasible? Um, hydrogen isn't polluting. Rockets burning pure H2 and O2 generate water.
Ian Woollard - 30 Jan 2006 19:17 GMT Hydrogen is quite polluting since it takes a lot of energy to manufacture; and a lot of CO2 and doubtless other pollutants get generated. The fact that it produces very little pollution when the rocket flies isn't really the point.
Fuels like bioethanol and don't produce net CO2 since the plants suck an equal amount of CO2 out of the air when they grow, so you're left with essentially no pollution - from the fuel anyway.
The rocket itself is a different story- aluminium needs quite a bit of energy to produce and CO2 is liberated during the electrolysis that makes it from the ore. Still, a BOTE calculation suggests that this is a much smaller amount of pollution than the fuel.
Damon Hill - 27 Jan 2006 17:52 GMT psturroc@gmail.com wrote in news:1138202258.435499.251660 @z14g2000cwz.googlegroups.com:
> Are there any rocket fuels -- existing or potential -- that are less > polluting than kerosene or hydrogen? If so, are any of them > economically feasible? Exactly how polluting are carbon dioxide and water?
There are no practical alternatives to existing chemistries. If anything, it's not a problem to begin with; these exhaust products are normal constituents of the atmosphere.
--Damon
Cray74@gmail.com - 27 Jan 2006 18:23 GMT I think it'd be hard to beat the hydrogen/oxygen propellant combination. The exhaust is water.
Mike Miller
Cruithne3753 - 27 Jan 2006 19:20 GMT > Are there any rocket fuels -- existing or potential -- that are less > polluting than kerosene or hydrogen? If so, are any of them > economically feasible? Hydrogen + oxygen = water vapour. Can't get any less polluting than that.
G. R. L. Cowan - 28 Jan 2006 19:02 GMT > > Are there any rocket fuels -- existing or potential -- that are less > > polluting than kerosene or hydrogen? If so, are any of them > > economically feasible? > > > Hydrogen + oxygen = water vapour. Can't get any less polluting than that. Actually water doesn't naturally tend to rise high in the stratosphere, so its release there by rockets or aircraft can be considered pollution, although not, in my opinion, of a very serious kind. I believe it freezes and fairly soon falls out.
A rocket with liquid air for propellant, powered by a laser on the ground, would be a little cleaner than an oxyhydrogen rocket. Isp probably would be much inferior, although in principle one could put a lot of laser power into heating a low mass flow rate of air from the rocket's tanks, and get a crazy chamber temperature in the middle of the chamber but not at the walls.
--- Graham Cowan, former hydrogen fan Boron fire good. http://tinyurl.com/4xt8g
Cray74@gmail.com - 29 Jan 2006 03:53 GMT > A rocket with liquid air for propellant, > powered by a laser on the ground, > would be a little cleaner than an oxyhydrogen rocket. If you kept the liquid air fairly cool when you zap it with a laser, sure. However, if you heat that liquid air with the laser to several thousand degrees, you're probably going to get a lot of nitrous oxides.
Mike Miller
Rick Jones - 27 Jan 2006 19:41 GMT > Are there any rocket fuels -- existing or potential -- that are less > polluting than kerosene or hydrogen? If so, are any of them > economically feasible? I'm neither a rocket scientist nor chemist, but my understanding is that the combustion product of Hydrogen and Oxygen (I'm ass-u-me-ing the rockets are using Oxygen as the oxidizer) is water and I suspect that is about as "non-polluting" as it gets.
Unless perhaps we start talking about things like rails and "beanstalks" and the like, but then those aren't devices using "rocket fuel" right?
rick jones
 Signature portable adj, code that compiles under more than one compiler these opinions are mine, all mine; HP might not want them anyway... :) feel free to post, OR email to rick.jones2 in hp.com but NOT BOTH...
Ian Woollard - 28 Jan 2006 02:23 GMT Yes, bioethanol and liquid oxygen. And yes, pretty feasible. You might also be able to use some suitable vegetable oils to replace kerosene with minimal modification to the engines. Doing it that way, you'd get minimal pollution (a bit of nitrates produced during the burn, but not too bad.)
Hydrogen is only less polluting if you make it in a non polluting way, but hydrogen is actually commercially manufactured from methane; is energy intensive and probably generates more CO2 than a rocket burning kerosene would.
(Manufacturing hydrogen from electrolysis of water using nuclear power, in principle is clean, but is never done on a large scale; the energy required is prohibitive.)
Patrick Schaaf - 29 Jan 2006 06:12 GMT >(Manufacturing hydrogen from electrolysis of water using nuclear power, >in principle is clean, Yeah. And the nuclear waste will be flung, using beanstalks made of hemp, right into the sun, where it can again be called nonpolluting...
best regards Patrick
David M. Palmer - 05 Feb 2006 07:23 GMT > >(Manufacturing hydrogen from electrolysis of water using nuclear power, > >in principle is clean, > > Yeah. And the nuclear waste will be flung, using beanstalks made > of hemp, right into the sun, where it can again be called nonpolluting... What? And upset the delicate ecology that may exist on the Sun? After you've polluted the Sun, an unprotected person standing on the surface would quickly die of radiation (even if they go at night).
 Signature David M. Palmer dmpalmer@email.com (formerly @clark.net, @ematic.com)
Lawrence Gales - 01 Feb 2006 08:02 GMT > Date: 27 Jan 2006 18:23:01 -0800 > From: Ian Woollard <ian.woollard@gmail.com> [quoted text clipped - 15 lines] > in principle is clean, but is never done on a large scale; the energy > required is prohibitive.) ----------------------------------------------- It is my undestanding that current large wind turbines create electricity at 4.5 cent/KWH (with no subsidies) on the average. At that rate it costs about $2 to produce an amount of H2 by electrolysis which, when burned in a fuel cell, is equal to a gallon of gasoline, when burned in a combustion engine. For automobile use you have to add another dollar for all the remaining costs of distribution, including profits. So $3/gallon equivalent of gasoline to produce H2 by electrolysis is hardly prohibitive
In fact the costs would be lower, because the 4.5 cents/KWH assume that you are using *clean* electricity to perform electrolysis. A major part of wind turbine costs is the conversion of mixed frequency current to direct current and then back to clean 60 cycle current -- something that is needed to run computers and TVs but not for electrolysis.
I don't know why this myth of high costs to clenaly produce H2 persists. However, H2 is only truly clean when burned in a fuel cell. When burned using combution it produces Nitrogen oxides.
-- Larry Gales
Ian Woollard - 10 Feb 2006 05:00 GMT According to: http://www.stardrivedevice.com/electrolysis.html a 'gallon equivalent' is 1kg of hydrogen and would in fact cost slightly over $4 to produce by electrolysing water. However, for rocketry purposes this neglects the liquification costs which are quite significant.
Last time I heard, NASA was purchasing their *liquid* hydrogen for about $7/kg, and that wasn't even environmentally friendly hydrogen, which is more expensive.
Damon Hill - 10 Feb 2006 08:20 GMT > According to: http://www.stardrivedevice.com/electrolysis.html a > 'gallon equivalent' is 1kg of hydrogen and would in fact cost slightly [quoted text clipped - 5 lines] > about $7/kg, and that wasn't even environmentally friendly hydrogen, > which is more expensive. So the only acceptable propellants are wind/solar powered electrolytically derived and liquified hydrogen and oxygen? We certainly don't want nuclear-comtaminated fuels, do we? (sarcasm)
--Damon
Ian Woollard - 12 Feb 2006 18:10 GMT On the contrary if you are a rocket engineer it's essential to use the most expensive propellant you can find, because that helps keeps the costs of rockets high, the launch volume low; and increases profits.
So on that basis nuclear produced hydrogen is a wonder fuel.
I was just pointing out that bioethanol was cheap to make sure that everyone here avoids using it in their rockets. Obviously.
David M. Palmer - 12 Feb 2006 19:51 GMT > > According to: http://www.stardrivedevice.com/electrolysis.html a > > 'gallon equivalent' is 1kg of hydrogen and would in fact cost slightly [quoted text clipped - 10 lines] > We certainly don't want nuclear-comtaminated fuels, do we? > (sarcasm) What is the ISP of a LOX-whale oil rocket?
 Signature David M. Palmer dmpalmer@email.com (formerly @clark.net, @ematic.com)
Jim Logajan - 29 Jan 2006 00:38 GMT > Are there any rocket fuels -- existing or potential -- that are less > polluting than kerosene or hydrogen? If so, are any of them > economically feasible? I'm surprised no one has suggested solar power. ;-)
A simple ground or space based variable-focus mirror and a solar-heated ramjet is all you need! Needs, ah, a few details worked out....
Sea Wasp - 29 Jan 2006 14:07 GMT > Are there any rocket fuels -- existing or potential -- that are less > polluting than kerosene or hydrogen? HYDROGEN???
When hydrogen burns, it releases H2O. While the dangers of dihydrogen oxide (more commonly called "water") are well known, it is generally not considered a pollutant.
 Signature Sea Wasp /^\ ;;; Live Journal: http://www.livejournal.com/users/seawasp/
H2-PV NOW - 14 Feb 2006 08:16 GMT > Are there any rocket fuels -- existing or potential -- that are less > polluting than kerosene or hydrogen? If so, are any of them > economically feasible? Potentially there are an infinite number of rocket propellents with minimally reacting emissions. A mass ejection system using an acceleration means to eject any inert mass will obey Newton's law of equal and opposite reaction. If you were smart enough you could eject sand, or marshmallows, or watermelons, fast enough to get a forward thrust from it.
Most people aren't smart enough, so they use chemical explosives to accomplish the task, beginning with gunpowder being used a thousand years ago for Chinese rockets for warfare and fireworks displays. Hydrogen Peroxide is an explosive used by some model rocketeers which is fairly benign environmentally and quite capable of causing fatal mishaps to the reckless experimenter.
As pointed out by many posters in this thread, Hydrogen and Oxygen as fuel is fairly clean under many circumstances, although high volume traffic in the Ozone layer might present a future problem, as Hydrogen is very reactive with ozone, so imperfectly burned H2+O2 could conceivably present a problem at this strata someday bye and bye.
Hydrogen by itself is not flamable. It requires oxidizer. H2+O2 outputs significant heat, which causes atmospheric Nitrogen to react with atmospheric Oxygen to make oxides of Nitrogen, called NOX, which further react to produce photochemical smog.
Any sufficiently hot fire or flame will do this, so all fiery rocket plumes do this to some extent no matter what is burning as fuel.
The problem is not so much a constant, as it is location dependent. That is to say a rocket fired from ground level will have ten times the density of air to react with as a rocket ignited at ten miles in altitude, so the chemical reaction potential is ten times greater at sea level.
There are proposals for balloon-assisted launches, or kite-assisted launches at high altitudes, primarily for the purposs of saving fuel to orbit, not as "clean" concepts. They would generate less NOX as a byproduct of saving fuel, but that is not their intent.
NASA was able to loft a 1,600 pound plastic airplane to 96,863 feet in 2001, powered only by solar photovoltaic cells and 28 horsepower of electric motors. That's 18.5 miles high, so there is some evidence that high altitude launchpads are worth considering.
SpaceShipOne was launched from 50,000 feet from a flying platform on a craft named White Knight, although it only attained a maximum height of one-third the altitude to the International Space Station. That was also a plastic rocket and plastic carrier plane. Perhaps if it launched from the peak altitude of the NASA Helios record It might have reached a low earth orbit.
The Take-Home Lesson should be that when you concern yourself about the environmental effects you seem to get cheaper launches and better results as a side-effect, or vice versa. Thinking cheaper produces less environmental impacts as a side-effect. Ultimately there will be no mass space transportation until people think a LOT CHEAPER. $10,000 per pound Space Shuttle cargos is not the route we want to pursue any longer than required to get the basic science data needed for $10/pound payloads. Even $10/pound to deliver packages 220 miles is a lot more than FedEx charges. 2,600,000 pounds of solid rocket exhaust makes a 1,300 tons of pollution. Think "CHEAPER" and you will get cleaner: think "CLEANER" and you will get cheaper.
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